Undergraduate coauthors underlined

Spring 2016: Professor Stockland's book on functional group synthesis starts shipping (February 2016)!

 

Resolved P-Metallated Nucleoside Phosphoramidites. E. J. Miller, K. J. Garcia, E. C. Holahan, R. M. Ciccarelli, R. A. Bergin, S. L. Casino, T. L. Bogaczyk, M. R. Krout, P. M. Findeis, and R. A. Stockland Jr. Inorg. Chem. 2014, 53, 12680.

Acid, silver, and solvent-free gold catalyzed hydrophenoxylation of internal alkynes. M. E. Richard, D. V. Fraccica, K. J. Garcia, E. J. Miller, R. M. Ciccarelli, E. C. Holahan, V. L. Resh, A. Shah, P. M. Findeis, and R. A. Stockland Jr. Beilstein J. Org. Chem. 2013, 9, 2002-2008. Invited contribution to a thematic series on gold catalysis edited by Dean Toste. Our paper was one of the top 10 most downloaded articles in October!

Rapid Synthesis of Arylgold Compounds Using Dielectric Heating. H.K. Lenker, T.G. Gray and R.A. Stockland Jr. Dalton Trans.2012, 41, 13274-13276.

Phospha-Michael Additions to Activated Internal Alkenes: Steric and Electronic Effects. Lenker, H, K.; Richard, M. E.; Reese, K. P.; Carter, A. F.; Zawisky, J. D.; Winter, E. F.; Bergeron, T. W.; Guydon, K. S.; Stockland, R. A., Jr. J. Org. Chem. 2012, 77, 1378-1385.

P-H activation using alkynylgold substrates: steric and electronic effects. Manbeck, G.F.; Kohler, M.C.; Porter, M.R.; Stockland, R.A.Jr. Dalton Trans. 2011, 40, 12595-12606. This paper has been selected as a "HOT Article" for 2011.

Probing the Steric Limits of Rhodium Catalyzed Hydrophosphinylation.  E-H addition vs. Dimerization/Oligomerization/Polymerization, M.E. Richard, K. P Reese, J. J. Stone, P. D. Pickett, E. S. Tillman, R. A. Stockland Jr., J. Organomet. Chem. 2011, 696, 123..  Invited contribution for a special issue on catalytic addition of E-H bonds to non-activated carbon-carbon multiple bonds

Luminescent Au(I)/Cu(I) Alkynyl Clusters with an Ethynyl Steroid and Related Aliphatic Ligands: an Octanuclear Au4Cu4 Cluster and Luminescence Polymorphism in Au3Cu2 Clusters. Manbeck, G. F.; Brennessel, W.W.; Stockland, R. A. Jr.; Eisenberg, R.  J. Am Chem. Soc. 2010, 132, 12307.

Microwave Heating as a Tool for Clean Organic Synthesis.  Stockland, R.A. Jr. in Microwave Heating as a Tool for Sustainable Chemistry. Nicholas Leadbeater, ed. CRC Press, 2010

Arylpalladium Phosphonate Complexes as Reactive Intermediates in Phosphorus-Carbon Bond Forming Reactions, Mark C. Kohler, T. V. Grimes, X. Wang,  T. R. Cundari, and R. A. Stockland Jr. Organometallics 2009, 28, 1193-1201.

Development of a Room Temperature Hirao Reaction, M.C.Kohler, J. G. Sokol, and R. A. Stockland Jr. Tetrahedron Lett. 2009, 50, 457.

Microwave Assisted Heterofunctionalization of Alkenes, D. Ide, M. Eastlund, C. Jupe, and R. A. Stockland Jr. Curr. Org. Chem. 2008, 12, 1258. (invited review)

Modern NMR Spectroscopy in Education, ACS symposium Series Volume 969, Eds. David S. Rovnyak and R. A. Stockland Jr., 2007.

Synthesis, Characterization, and Reactivity of a Hexane Soluble Silver Salt. R. A. Stockland Jr., B. D. Wilson, C. C. Goodman, B. J. Giese, and F. L. Shrimp II J. Chem. Ed. 2007, 84, 694.

Steric and Electronic Effects on Arylphosphonate Elimination from Organopalladium Complexes. M. C. Kohler, R. A. Stockland Jr., and N. P. Rath Organometallics 2006, 25, 5746.

Organometallic Complexes Containing 17-Ethynyl-17 b -hydroxyandrost-4-en-3-one and Related Ethynyl Steroids. R. A. Stockland Jr., M. C. Kohler, I. A. Guzei, Margaret E. Kastner, and J. A. Bawiec, III, R. B. Hochberg, D. C. Labaree Organometallics, 2006, 25, 2475.

Remarkable tolerance of ethynyl steroids to air and water in hydrophosphinylation reactions: Reaction scope and limitations. R. A. Stockland Jr. A. J. Lipman, J. A. Bawiec, P. E. Morrison, I. A. Guzei, P. M. Findeis, J. F. Tamblin. J. Organomet. Chem. 2006, 691, 4042.

Microwave Assisted Regioselective Addition of P(O)-H Bonds to Alkenes Without Added Solvent or Catalyst. R.A. Stockland Jr., R. I. Taylor, L.E. Thompson, P.B. Patel. Org. Lett. 2005, 7, 851.

Organosoluble Copper Clusters as Precatalysts for Carbon-Heteroelement Bond Forming Reactions: Microwave and Conventional Heating. G. F. Manbeck, A. J. Lipman, R. A. Stockland Jr., A. L. Freidl, A. F. Hasler, J. J. Stone, and I. A. Guzei J. Org. Chem. 2005, 70, 244.

Microwave Assisted Single and Double Addition of HP(O)Ph2 to Alkynes. J. J. Stone, R. A. Stockland Jr., J. Kovach, J. M. Reyes Jr., Caton C. Goodman, and E. S. Tillman J. Mol. Catal. A: Chemical 2005, 226, 11.

Fluxional Organometallic and Coordination Compounds. R. A. Stockland Jr. Appl. Organomet. Chem. (invited book review) 2005, 19, 1274.

Reductive Elimination from Metal Phosphonate Complexes: Circumvention of Competing Protonolysis Reactions. R. A. Stockland Jr., A. M. Levine, M. T. Giovine; I. A. Guzei, and J. C. Cannistra Organometallics 2004, 23, 647.

Diphenyl (3,3-diphenoxycyclohexyl)-phosphonate. I. A. Guzei, R. A. Stockland Jr. and T. W. Tennis Acta Cryst., E 2003, 59, o129.

Coupling of Aryl Halides with Aryl Boronic Acids using P(C6H5)(2-C6H4Cl)2 as the Supporting Ligand. M. R. Pramick, S. M. Rosemeier, M. T. Beranek, S. B. Nickse, J. J. Stone, R. A. Stockland Jr., S. M. Baldwin, and M. E. Kastner Organometallics 2003, 22, 523.

Transition metal complexes containing P(C6H4Cl-2)2(C6H5). The effect of added Lewis bases as a probe for substitution reactions occurring in ambient temperature Suzuki couplings catalyzed by Pd/ P(C6H4Cl-2)2(C6H5). J. J. Stone, Robert A. Stockland, Jr., and Nigam P. Rath Inorg. Chim. Acta 2003, 342, 236.

Direct Observation of P(O)-C(sp3) Bond Formation from (N^N)PdMe(P(O)(OPh)2) Complexes. Rate Enhancement of reductive elimination by addition of Triarylphosphines., A. M. Levine, R. A. Stockland Jr., R. Clark, and I. A. Guzei, Organometallics 2002, 21, 3278.


Publications from graduate and postdoctoral work

Reaction of Vinyl Chloride With Late Transition Metal Olefin Polymerization Catalysts. Stephen R. Foley, Robert A. Stockland, Jr., Han Shen, and Richard F. Jordan J. Am. Chem. Soc. 2003, 125, 4350.

Reaction of Vinyl Chloride with Group 4 Metal Olefin Polymerization Catalysts, R. A. Stockland Jr., Stephen R. Foley, Richard F. Jordan. J. Am. Chem. Soc. 2003, 125, 796.

Reaction of Vinyl Chloride with Olefin Polymerization Catalysts, R. F. Jordan, R. A. Stockland, Jr.; H. Shen, S. Foley, Polym. Mat. Science and Engineering 2002, 87, 39.

A General Route to Halide-Bridged Organopalladium A-Frame Complexes, and Studies of Reductive Elimination from these Bimetallic Systems. R. A. Stockland Jr., M. Janka, G. R. Hoel, and G. K. Anderson Organometallics 2001, 20, 5212.

Reaction of Vinyl Chloride with a Prototypical Metallocene Catalyst: Stoichiometric Insertion and beta-Cl elimination Reactions with rac-(EBI)ZrMe+ and Catalytic Dechlorination/Polymerization to Oligopropylene by rac-(EBI)ZrMe2/MAO R. A. Stockland, Jr. and R. F. Jordan J. Am. Chem. Soc. 2000, 122, 6315-6316.

The Bis(cyclopentadienyl)(methyl)Zirconium(IV)methyltris(pentafluorophenyl)borate ion pair. I. A. Guzei, R. A. Stockland, Jr., R. F. Jordan Acta Crystallogr., Sect. C 2000, C56, 635.

Preparation and solution behavior of diphosphinepalladium nitrite complexes. J. A. Moser, R. A. Stockland, Jr., and G. K. Anderson Polyhedron 2000, 19, 1329.

Synthesis and structure of hydride-bridged palladium complexes. R. A. Stockland, Jr., G. K. Anderson, and N. P. Rath Inorg. Chim. Acta 2000, 300, 395.

Reductive Elimination of Alkanes and Arenes from [Pd2R2(u-H)(u-dppm)2]PF6 Complexes. R. A. Stockland, Jr., G. K. Anderson, and N. P. Rath J. Am. Chem. Soc. 1999, 121, 7945.

[Bis(diphenylphosphino)methane]dinitropalladium(II) tris(deuteriochloroform) solvate. N. P. Rath, R. A. Stockland, Jr., and G. K. Anderson Acta Crystallogr., Sect. C 1999, 55, 494.

Demethylation of Trimethylphosphite Promoted by Dichlorodiphosphineplatinum and Palladium Complexes. Structures of the Metallophosphonate Complexes, [Pt(P^P){P(O)(OMe)2}2] (P^P = dppe, dppp). R. A. Stockland, Jr., D. L. Maher, G. K. Anderson, and N. P. Rath Polyhedron 1999, 18, 1067.

Fluxional Behavior of Cyclooctenylpalladium Acetylacetonate and Related Complexes. R. A. Stockland, Jr. and G. K. Anderson Organometallics 1998, 17, 4694.

Nucleophilic Attack on Cyclooctadiene Complexes of Palladium. Stereochemistry of the Resulting Cyclooctenylpalladium Derivatives. G. R. Hoel, R. A. Stockland, Jr., G. K. Anderson, F. T. Ladipo, J. Braddock- Wilking, N. P. Rath, and J. C. Mareque-Rivas Organometallics 1998, 17, 1155.

Unusual Cyanide-Bridged Extended A-frame Complex: the Molecular Structure of [{Pd2Br2(PPh2)(dppm)}2(CN)2]. R. A. Stockland, Jr., G. K. Anderson, and N. P. Rath Inorg. Chim. Acta 1998, 271, 236.

Reactions of [PdX2(dppm)] complexes with Grignard reagents. R. A. Stockland, Jr., G. K. Anderson, and N. P. Rath Organometallics 1997, 16, 5096.

Hydride-Bridged Dipalladium Complexes Containing Diphosphine Ligands. R. A. Stockland, Jr., G. K. Anderson, and N. P. Rath Inorg. Chim. Acta 1997, 259, 173 (Special issue on metal-hydrides).

Synthesis of the complexes [PdClR(cod)] (R= benzyl, ethyl; cod = 1,5 cyclooctadiene). Beta-Elimination from [PdClEt(cod)] to give the isomers of [Pd2(u-Cl)2(C8H13)2]. R. A. Stockland, Jr., G. K. Anderson, N. P. Rath, J. Braddock-Wilking, and J. C. Ellegood Can. J. Chem. 1996, 74, 1990.